CH 2303 CHEMICAL ENGINEERING THERMO DYNAMICS I SYLLABUS | ANNA UNIVERSITY B.TECH. CHEMICAL ENGINEERING 5TH SEMESTER SYLLABUS REGULATION 2008 2011 2012-2013 BELOW IS THE ANNA UNIVERSITY FIFTH SEMESTER B.TECH. CHEMICAL ENGINEERING DEPARTMENT SYLLABUS, TEXTBOOKS, REFERENCE BOOKS, IT IS APPLICABLE FOR ALL STUDENTS ADMITTED IN THE YEAR 2011 2012-2013 (ANNA UNIVERSITY CHENNAI,TRICHY,MADURAI,TIRUNELVELI,COIMBATORE), 2008 REGULATION OF ANNA UNIVERSITY CHENNAI AND STUDENTS ADMITTED IN ANNA UNIVERSITY CHENNAI DURING 2009
CH 2303 CHEMICAL ENGINEERING THERMO DYNAMICS I L T P C
3 0 0 3
AIM
To present thermodynamic principles from a chemical engineering viewpoint.
OBJECTIVES
The Students will be well versed with the behavior of fluids under PVT conditions and
also apply them for practical purpose. Main advantage will be to deal with power
production and refrigeration processes. The study further provides a comprehensive
exposition to theory and application of solution thermodynamics.
UNIT I BASIC CONCEPTS 6
The terminologies of thermodynamics, the variables and quantities of thermodynamics,
categorization of systems and processes. Energy classifications, point and path
properties, energy in transition, heat and work, reversible and irreversible processes,
phase rule.
UNIT II LAWS OF THERMODYNAMICS 12
The first law and internal energy, statements of first law for the non flow and flow
systems, enthalpy and heat capacity limitations of the first law.
Statements of the second law of thermodynamics, available and unavailable energies,
and the entropy function, applications of the second law.
UNIT III THERMODYNAMIC PROPERTIES OF REAL GASES 9
The PVT behavior of fluids, laws of corresponding states and equation of states
approaches to the PVT relationships of non ideal gas, problems; compressibility factors,
generalized equations of state, property estimation via generalized equation of state;
fugacity and fugacity coefficients of real gases.
43
UNIT IV THERMODYNAMIC FORMULATIONS 9
Measurable quantities, basic energy relations, Maxwell relations, thermodynamic
formulations to calculate enthalpy, internal energy and entropy as function of pressure
and temperature, other formulations involving Cp and Cv, complex thermodynamic
formulations, thermodynamic properties of an ideal gas, entropy change in reversible
and irreversible process.
UNIT V COMPRESSION OF FLUIDS 9
Thermodynamic aspects of compression process, classification of compression
processes, basic equation for change of state of gases, the work expression for different
situations, the effect of clearance volume, multistage compression, convergent divergent
flow, Ejectors.
TOTAL : 45 PERIODS
TEXT BOOKS
1. Smith, J.M., VanNess, H.C., & Abbot M.C, “Introduction to Chemical Engineering
Thermodynamics”, McGraw Hill VII Edition 2004.
2. Narayanan K.V “A Text Book of Chemical Engineering Thermodynamics” Prentice
Hall of India Pvt. Ltd. 2001.
REFERENCES
1. Hougen, O.A., Watson, K.M., and Ragatz, R.A., “Chemical Process Principles Part
II, Thermodynamics”, John Wiley 1970.
2. Dodge, B.F., “Chemical Engineering Thermodynamics”, McGraw-Hill, 1960.
3. Sandler, S.I., “Chemical and Engineering Thermodynamics 2nd edn.”, Wiley, 1989.
4. Kyle, B.G., “Chemical and Process Thermodynamics 2nd edn.”, Prentice Hall of
India Pvt. Ltd., 1990.
CH 2303 CHEMICAL ENGINEERING THERMO DYNAMICS I L T P C
3 0 0 3
AIM
To present thermodynamic principles from a chemical engineering viewpoint.
OBJECTIVES
The Students will be well versed with the behavior of fluids under PVT conditions and
also apply them for practical purpose. Main advantage will be to deal with power
production and refrigeration processes. The study further provides a comprehensive
exposition to theory and application of solution thermodynamics.
UNIT I BASIC CONCEPTS 6
The terminologies of thermodynamics, the variables and quantities of thermodynamics,
categorization of systems and processes. Energy classifications, point and path
properties, energy in transition, heat and work, reversible and irreversible processes,
phase rule.
UNIT II LAWS OF THERMODYNAMICS 12
The first law and internal energy, statements of first law for the non flow and flow
systems, enthalpy and heat capacity limitations of the first law.
Statements of the second law of thermodynamics, available and unavailable energies,
and the entropy function, applications of the second law.
UNIT III THERMODYNAMIC PROPERTIES OF REAL GASES 9
The PVT behavior of fluids, laws of corresponding states and equation of states
approaches to the PVT relationships of non ideal gas, problems; compressibility factors,
generalized equations of state, property estimation via generalized equation of state;
fugacity and fugacity coefficients of real gases.
43
UNIT IV THERMODYNAMIC FORMULATIONS 9
Measurable quantities, basic energy relations, Maxwell relations, thermodynamic
formulations to calculate enthalpy, internal energy and entropy as function of pressure
and temperature, other formulations involving Cp and Cv, complex thermodynamic
formulations, thermodynamic properties of an ideal gas, entropy change in reversible
and irreversible process.
UNIT V COMPRESSION OF FLUIDS 9
Thermodynamic aspects of compression process, classification of compression
processes, basic equation for change of state of gases, the work expression for different
situations, the effect of clearance volume, multistage compression, convergent divergent
flow, Ejectors.
TOTAL : 45 PERIODS
TEXT BOOKS
1. Smith, J.M., VanNess, H.C., & Abbot M.C, “Introduction to Chemical Engineering
Thermodynamics”, McGraw Hill VII Edition 2004.
2. Narayanan K.V “A Text Book of Chemical Engineering Thermodynamics” Prentice
Hall of India Pvt. Ltd. 2001.
REFERENCES
1. Hougen, O.A., Watson, K.M., and Ragatz, R.A., “Chemical Process Principles Part
II, Thermodynamics”, John Wiley 1970.
2. Dodge, B.F., “Chemical Engineering Thermodynamics”, McGraw-Hill, 1960.
3. Sandler, S.I., “Chemical and Engineering Thermodynamics 2nd edn.”, Wiley, 1989.
4. Kyle, B.G., “Chemical and Process Thermodynamics 2nd edn.”, Prentice Hall of
India Pvt. Ltd., 1990.
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